Process for no-bake foundry application utilizing polyurethanes based on amine polyols

ABSTRACT

No Bake foundry cores and molds for casting metals are prepared by using a binder comprising a polyol generally derived from alkoxylating an amine compound and a polyisocyanate. The binder is especially useful for casting non-ferrous metals, for example, the casting of aluminum, magnesium and other light weight metals. The cores and molds produced for casting aluminum and other light weight metals exhibit excellent shakeout while retaining other desirable core and mold properties. In addition the binders of this invention would have been observed to have an autocatalytic nature.

This is a continuation of Ser. No. 072,730 filed Sept. 4, 1979 whichSer. No. 072,730 was a continuation of Ser. No. 915,413 filed June 14,1978, both now abandoned.

BACKGROUND OF THE INVENTION

This invention relates to resinous binder compositions which areadmixtures of amine-based polyols and polyisocyanates. In another aspectthis invention relates to curable urethane binder compositions which areuseful for binding particulate solids. In particular the inventionrelates to binders, of the No Bake type, which utilize an amine polyol.The binders are capable of bonding sand or other foundry aggregate toform molds or cores for casting of metals, especially aluminum and otherlight weight metals which are cast at relatively low temperature. Thecores and molds made using these binders demonstrate superiorcollapsibility when used at low casting temperatures.

DESCRIPTION OF THE PRIOR ART

Urethane No Bake binders for use in bonding aggregates useful as foundrycores and molds are known in the art. U.S. Pat. No. 3,676,392 is anexample of such a No Bake binder composition and the use thereof to makecores and molds for foundry applications.

This invention is based in part upon the autocatalytic nature of aminepolyols. A No Bake binder system for use in foundries is now disclosedwhich can be a two component system instead of a typical urethane NoBake System which utilizes at least three components.

Although the autocatalytic nature is a significant advancement, thisinvention is not limited to such a system but may also incorporate acatalyst in certain embodiments. It is believed that utilization of anamine polyol in a No Bake System is in itself an advancement in the artof foundry binders.

This invention also embodies another very important feature. A long feltneed in the foundry industry has been a No Bake binder for makingcastings for light metals such as aluminum and magnesium. The No Bakebinders of the prior art were unable to provide cores and molds forcasting these light weight metals having the required core and moldproperties as well as good shakeout. Urethane No Bake binders based onphenolic, alkyd-oil and polyester polyols are common in the foundryindustry. However, when enough binder is used to achieve workablestrength and abrasion resistance the cores and molds will not break downwell at the casting temperatures of light metals. That is, theyexhibited poor shakeout. Non-urethane No Bake binders based on furanresins, phenolic resins, alkyd resins, phosphate polymers and sodiumsilicates are also known and used, but suffer from the same shakeoutproblem as described for the urethane No Bake binders. Therefore, anexisting problem has been to find a binder that on the one hand producesstrong, non-friable cores and molds and on the other hand breaks downwell at the casting temperature of aluminum and magnesium to provideeasy shakeout.

BRIEF SUMMARY OF THE INVENTION

It is an object of this invention to provide a foundry bindercomposition using in admixture a polyol and a polyisocyanate, whereinthe polyol is an amine polyol. The amine polyols of this invention arenormally obtained as the reaction product of an amine and an alkyleneoxide.

Another object of this invention is to provide urethane No Bake bindercompositions. It is further an object of this invention to provideurethane No Bake binders which can be used to produce cores and moldswhich have strength and non-friability but still break down well at lowcasting temperatures, i.e., below the casting temperatures of ferrousmetals. The cores and molds exhibit the combination of strength and easyshakeout at the casting temperatures of light weight metals such asaluminum and magnesium.

It has been found that a urethane binder formed as the reaction productof a polymeric isocyanate and an amine-based polyol can be used to makecores and molds. More specifically it has been found that a polyol whichis the reaction product of an amine compound and an alkylene oxide willreact with a polymeric isocyanate to produce a No Bake binder which,upon mixing with sand or other suitable foundry aggregates, forms coresand molds possessing excellent working characteristics, i.e., strength,abrasion resistance and non-friability. These properties are coupledwith excellent shakeout characteristics when used in casting nonferrousmetals. This combination of good working characteristics and excellentshakeout are especially significant and unique when the binder is usedto make cores intended for use in low temperature casting. A catalyst isnot necessarily a component of the binder system. However, suitablecatalysts can be utilized in the invention and are preferred withcertain amine polyols when a rapid cure is needed.

DETAILED DESCRIPTION OF THE INVENTION

The resin compositions of the present invention find use as a two-partcomposition or system. Part one is the amine polyol. Part two is thepolyisocyanate. Both parts are in liquid form and are generallysolutions with organic solvents. At the time of use, that is to say whenthe urethane binder is formed, the amine polyol part and thepolyisocyanate part are combined and used for the intended application.In foundry application, i.e., the use of the compositions as a binderfor cores and molds, it is preferred to first admix one part with afoundry aggregate such as sand. Thereafter, the second component isadded and after achieving a uniform distribution of binder on theaggregate, the resulting foundry mix is formed or shaped into thedesired shape. The shaped product can immediately be set aside and willcure to form a core or mold at room temperature. The compositions ofthis invention are generally autocatalytic to a degree. That is, oncethe amine polyol and isocyanate are combined the reactivity of thepolyol with the isocyanate is such that the reaction proceeds rapidlyenough that a catalyst is not needed. The degree of reactivity of theamine polyol and polyisocyanate is dependent upon the reactivity of thepolyol.

In spite of the fact that the compositions are autocatalytic, aminecatalysts and metallic catalysts known in urethane technology may beemployed. It should be noted that in some cases the use of a catalystwith the amine polyol and polyisocyanate components is beneficial andpreferred. By selection of a proper catalyst, conditions of the coremaking process, for example work time and strip time, can be adjusted asdesired. In commercial practice it may be necessary to use a catalystwith certain polyols to obtain desired production rates.

The amine polyols used to form the urethane binder compositions of thisinvention are normally produced as the reaction product of an alkyleneoxide and an amine compound. When the term "amine polyol" is used hereinit is meant to identify such reaction products but is not limitedspecifically to such means of synthesis. In general any polyolcontaining at least one or more tertiary amine groups are considered tobe within the scope of the definition of "amine polyol". The alkyleneoxides which are used to prepare the amine polyols are preferablyethylene oxide and propylene oxide. However, it appears feasible to useother alkylene oxides as well. The amount of alkylene oxide in moles tomoles of amine compound is subject to considerable variation. It isbelieved that the degree of alkoxylation does not detract from theability of the resultant amine polyol to function as a binder.

The amine compounds which react with alkylene oxides to yield the aminepolyols useful in the binder composition constituting this inventioninclude ammonia and mono and polyamino compounds with primary orsecondary amino nitrogens. Specific examples include aliphatic aminessuch as primary alkyl amines, ethylene diamine, diethylene triamine andtriethylene tetramine, cycloaliphatic amines, aromatic amines, such asortho-, meta- and para-phenylene diamines, aniline-formaldehyde resinsand the like. Blends of the amine polyols listed above can also beutilized. In addition a blend of amine polyols with other polyols isuseful. In general it is believed that amine containing compounds whichwhen alkoxylated yield a polyol with two or more reactive hydroxylgroups are useful in the compositions of this invention.

The second component or package of the novel binder compositioncomprises an aliphatic, cycloaliphatic, or aromatic polyisocyanatehaving preferably from 2 to 5 isocyanate groups. If desired, mixtures ofpolyisocyanates can be employed. Isocyanate prepolymers formed byreacting excess polyisocyanate with polyhydric alcohol e.g. a prepolymerof toluene diisocyanate and ethylene glycol, also can be employed.Suitable polyisocyanates include the aliphatic polyisocyanates such ashexamethylene diisocyanate, alicyclic polyisocyanates such as4,4'-dicyclohexylmethane diisocyanate, and aromatic polyisocyanates suchas 2,4- and 2,6-toluene diisocyanate, diphenylmethane diisocyanate, andthe dimethyl derivatives thereof. Further examples of suitablepolyisocyanates are 1,5-naphthalene diisocyanate, triphenylmethanetriisocyanate, xylylene diisocyanate, and the methyl derivativesthereof, polymethylenepolyphenyl isocyanates, chlorophenylene-2,4-diisocyanate, and the like. Although all polyisocyanates react withthe amine polyol to form a crosslinked polymer structure, the preferredpolyisocyanates are aromatic polyisocyanates and particularlydiphenylmethane diisocyanate, triphenylmethane triisocyanate, andmixtures thereof.

The polyisocyanate is generally employed in approximately astoichiometric amount, that is in sufficient concentration to cause thecuring of the amine polyol. However, it is possible to deviate from thisamount within limits and in some cases advantages may result. Ingeneral, the polyisocyanate will be employed in a range of 10 to 500weight percent based on the weight of the amine polyol. Preferably, from20 to 300 weight percent of polyisocyanate on the same basis isemployed. The polyisocyanate is employed in liquid form. Liquidpolyisocyanates can be employed in undiluted form. Solid or viscouspolyisocyanates are employed in the form of organic solvent solutions,the solvent being present in a range of up to 80% by weight of thesolution.

Although the solvent employed in combination with either the aminepolyol or the polyisocyanate or for both components does not enter toany significant degree into the reaction between the isocyanate and theamine polyol, it can affect the reaction. Thus the difference in thepolarity between the polyisocyanate and the amine polyol restricts thechoice of solvents in which both components are compatible. Suchcompatibility is necessary to achieve complete reaction and curing ofthe binder compositions of the present invention. Polar solvents ofeither the protic or aprotic type are good solvents for the aminepolyol. It is therefore preferred to employ solvents or combinations ofsolvents where the solvent(s) for the polyol and for the polyisocyanatewhen mixed are compatible. In addition to compatibility the solvents foreither the polyol or polyisocyanate are selected to provide lowviscosity, low odor, high boiling point and inertness. Examples of suchsolvents are benzene, toluene, xylene, ethylbenzene, and mixturesthereof. Preferred aromatic solvents are solvents and mixtures thereofthat have a high aromatic convent and a boiling point range within arange of 280° to 500° F. The polar solvents should not be extremelypolar such as to become incompatible when used in combination with thearomatic solvent. Suitable polar solvents are generally those which havebeen classified in the art as coupling solvents and include furfural,Cellosolve, glycol diacetate, butyl Cellosolve, acetate, isophorone andthe like. It is possible some reactive polyols may also be used as asolvent. In addition it should be noted that water has been found to bea suitable solvent for the amine polyol under certain conditions.

The binder components are combined and then admixed with sand or asimilar foundry aggregate to form the foundry mix or the foundry mix canalso be formed by sequentially admixing the components with theaggregate. Methods of distributing the binder on the aggregate particlesare well-known to those skilled in the art. The foundry mix can,optionally, contain other ingredients such as iron oxide, ground flaxfibers, wood cereals, pitch, refractory flours, and the like. Theaggregate, e.g. sand, is usually the major constituent and the binderportion constitutes a relatively minor amount. Although the sandemployed is preferably dry sand, some moisture can be tolerated. This isparticularly true if the solvent employed is non-water-miscible or if anexcess of the polyisocyanate necessary for curing is employed, sincesuch excess polyisocyanate will react with the water which as previouslymentioned has been found to be a solvent for some amine polyols.

As previously stated the excellent shakeout or collapsibility of coresmade using the binder of this invention is deemed to be a significantdiscovery. The binders of this invention degrade or break down easily topermit separation of the core from the cast metal. For castings at lowtemperatures, e.g. 1800° F. or below, shakeout has been a major problem.Generally nonferrous metals are cast at these temperatures includingaluminum and magnesium. Failure of the binder to break down causes greatdifficulty in removal of the sand from the casting. Thus coresexhibiting a low degree of shakeout or collapsibility, that is to say alow degree of binder degradation, require more time and energy to removethe sand from the casting. The use of the binder compositions of thisinvention results in many cases of virtually 100% shakeout without theapplication of any external energy. The improvement in shakeout isattributable to the presence of the amine polyol in the bindercomposition. As will be appreciated by those skilled in the art, theability of any core to shakeout is dependent to an extent upon theamount of binder used to bond the sand particles into a coherent shape.

The percent binder utilized based on the weight of the sand, dependsupon the desired core properties which are required from the bindersystem. As can be appreciated, as the amount of binder in the systemincreases an increase in the tensile strength of the core generallyoccurs. Accordingly, the binder level may be varied within reasonablelimits to achieve the described performance properties. A preferredrange of binder is, in this invention, from 0.7% to 2.5% based upon theweight of sand. However, it may be possible to use as little as 0.5% andas much as 10% binder and still achieve properties which are ofadvantage in certain applications. However, it has also been noted thatwhen the binder level is increased the degree of shakeout may decreaseat the higher binder levels.

The present invention is further illustrated by the following examplesin which, unless otherwise indicated, all parts are by weight and allpercentages are weight percentages.

EXAMPLE 1

An amine polyol was prepared by propoxylating 1.0 mole of ethylenediamine with 4.2 moles of propylene oxide. A 40% solids solution of theamine polyol was prepared by dissolving the polyol in an aromaticsolvent commercially available under the brand name HISOL® 10. Thesolution is referred to as Part I. A polymeric isocyanate solution, 75%solids, based on Mondur MR, commercially available from Mobay, wasproduced using an aromatic solvent, also HISOL® 10. The isocyanatesolution is referred to as Part II.

Wedron 5010 sand (washed and dried, fine grained silica sand, AFSGFN 66)was placed in a suitable mixing apparatus. Part I was admixed with thesand until a uniform coating was provided. Part II was added to thecoated sand and blended until a homogeneous sand mix was prepared. Anear stoichiometric amount of polyisocyanate, a slight excess, tocompletely react with the hydroxyl groups of the polyol was used. One ana half percent (11/2%) of total binder (equal amounts of Part I and II)by weight of sand was used.

The mix of sand, polyol and polyisocyanate was placed in a core box andstandard tensile briquettes, known as "dog bones", were prepared. A worktime of five and a half minutes and a strip time of eight minutes wasachieved. Tensile strengths after two hours, four hours and 24 hourswere 300, 371 and 387 psi, respectively.

The "dog bone" cores were used in shakeout studies with aluminumcastings. Seven tensile briquettes (dog bones) were arranged in a mold.The mold incorporated a gating system. The mold is designed to providehollow castings having a metal thickness of approximately one-quarterinch on all sides. An opening at an end of the casting is provided forremoval of the core from the casting. Molten aluminum at approximately1300° F. prepared from aluminum ingots was poured into the mold. Aftercooling for about an hour the aluminum castings are broken from thegating system and removed from the mold for shakeout testing.

Shakeout tests are performed by placing a casting in a one galloncontainer. The container is placed on an agitating mechanism and tumbledfor two minutes. The weight of the sand core which is removed from thecasting in this manner is compared to the initial weight of sand coreand a percent shakeout is calculated. Sand remaining in the castingafter the agitation described above is removed by scraping and alsoweighed. The sand core, bonded with the amine polyol-polyisocyanatebinder described above, collapsed and flowed out of the aluminum castingwithout using the agitation mechanism and without the application of anyexternal mechanical energy. Shakeout was 100%.

EXAMPLES 2-6

Using the procedures described in Example 1 dog bone test cores wereprepared using the components and methods listed and described below.The cores were used in shakeout tests using aluminum castings asdescribed in Example 1.

    __________________________________________________________________________             Example 2                                                                            Example 3                                                                              Example 4                                                                              Example 5                                                                            Example 6                            __________________________________________________________________________    Sand     Wedron Wedron   Wedron   Wedron Wedron                                        5010   5010     5010     5010   5010                                 Amine com-                                                                             Diethylene      Triethylene                                                                            Ethylene                                    pound    Triamine        Tetramine                                                                              Diamine                                     Alkylene Propylene       Propylene                                                                              Propylene                                   Oxide (AO)                                                                             Oxide           Oxide    Oxide                                       Mole Ratio                                                                             5.1:1           6.2:1    12:1                                        AO:amine                                                                      Amine           Triethanol-              QUADROL.sup.b                        Polyol          amine from                                                                    UPJOHN.sup.a                                                  Poly-    Mondur MR                                                                            Mondur MR                                                                              Mondur MR                                                                              Mondur MR                                                                            Mondur MR                            isocyanate                                                                    Solvent in                                                                             40%    10%      60%      60%    60%                                  Amine Polyol                                                                           HISOL 10                                                                             ISOPHORONE                                                                             ISOPHORONE                                                                             HISOL 10                                                                             HISOL 10                             Solvent in                                                                             NONE   NONE     25%      25%    25%                                  Polyisocyanate           HISOL 10 HISOL 10                                                                             HISOL 10                             Catalyst NONE   NONE     NONE     NONE   NONE                                 Work Time                                                                              5 min. 2 min.   0.5 min. 6 min. 5 min.                               Strip Time                                                                             12 min.                                                                              4.5 min. 1.0 min. 9 min. 8 min.                               Percent  1.5%   1.5%     1.5%     1.5%   1.5%                                 Binder                                                                                 40% Part I                                                                           50% Part I                                                                             50% Part I                                                                             50% Part I                                                                           50% Part I                                    60% Part II                                                                          50% Part II                                                                            50% Part II                                                                            50% Part II                                                                          50% Part II                          Tensile Strength                                                              in psi                                                                        2 hr.    100    153      85       360    339                                  4 hr.    118    210      113      365    350                                  24 hr.   163    247      --       230    383                                  Shakeout 100%   100%     100%     100%   100%                                 __________________________________________________________________________     .sup.a UPJOHN is a brand of triethanolamine, i.e. ethoxylated ammonia,        commercially available from Upjohn Corp.                                      .sup.b QUADROL is the brand of propoxylated ethylene diamine, mole ratio      of 4:1, commercially available from BASF Wyandotte.                      

Cores made as described above were observed to collapse and flow out ofthe casting without using an agitation mechanism and without theapplication of any external mechanical energy.

EXAMPLE 7

An aromatic amine polyol was prepared by propoxylating one mole ofmeta-phenylenediamine with 4.2 moles of propylene oxide. A 40% solidssolution of the aromatic amine polyol was prepared by dissolving thepolyol in an aliphatic solvent, butyl Cellosolve. This solution isreferred to as Part I. A polymeric isocyanate solution, 75% solids,based on Mondur MR, commercially available from Mobay, was preparedusing an aromatic solvent, commercially available as HISOL® 10. Theisocyanate solution is referred to as Part II. A nearly stoichiometricamount of polyisocyanate to completely react with the hydroxyl groups ofthe polyol was used.

Wedron 5010 sand (washed and dried, fine grained silica sand, AFSGFN 66)was placed in a suitable mixing apparatus. Part I was admixed with thesand until a uniform coating was provided. Incorporated in Part I was aurethane catalyst, triethylenediamine, commercially available under thebrand name DABCO. This catalyst is a well known urethane catalyst. Basedon the weight of Part I, 0.8% catalyst was used. Part II was added tothe coated sand and blended until a homogeneous sand mix was prepared.One and a half percent (11/2%) of total binder (Part I and Part II) byweight of sand was used.

The mix of sand, polyol, catalyst and polyisocyanate was placed in acore box and standard tensile briquettes, known as "dog bones", wereprepared. A work time of seventy minutes and a strip time of one hundredten minutes was achieved. Tensile strength after 24 hours was 230 psi.

The "dog bone" cores were used in shakeout studies as described inExample 1. Shakeout was 100%.

EXAMPLE 8-11

Using the procedures described in Example 7 dog bone test cores wereprepared using the components and methods as described below. The coreswere used in shakeout tests using aluminum castings as described inExample 7.

    __________________________________________________________________________               Example 8                                                                            Example 9                                                                            Example 10                                                                           Example 11                                    __________________________________________________________________________    Sand       Wedron Wedron Wedron Wedron                                                   5010   5010   5010   5010                                          Amine                                                                         Component                                                                     Alkylene                                                                      Oxide                                                                         Mole Ratio                                                                    AO:amine                                                                      Amine Polyol                                                                             Pluracol.sup.c                                                                       Pluracol.sup.c                                                                       Pluracol.sup.d                                                                       Pluracol.sup.d                                           767    767    795    795                                           Poly-      Mondur MR                                                                            Mondur MR                                                                            Mondur MR                                                                            Mondur MR                                     isocyanate                                                                    Solvent in 40%    35%    35%    35%                                           Amine Polyol                                                                             HISOL 10                                                                             Water  HISOL 10                                                                             HISOL 10                                      Solvent in 44%.sup.e                                                                            None   35%.sup.e                                                                            35%.sup.e                                     Polyisocyanate                                                                Catalyst (1)                                                                             1.4%   None   None   (1) 11%                                       Work Time  25 min.                                                                              10 min.                                                                              11.5 min.                                                                            7 min.                                        Strip Time 31 min.                                                                              16 min.                                                                              16 min.                                                                              10.5 min.                                     Percent    1.5%   1.7%   1.5%   1.5%                                          Binder                                                                                   50% Part I                                                                           60% Part I                                                                           50% Part I                                                                           50% Part I                                               50% Part II                                                                          40% Part II                                                                          50% Part II                                                                          50% Part II                                   Tensile Strength in psi                                                       2 hr.      225    108    203    223 (3 hrs.)                                  4 hr.      --     128 (3 hr)                                                                           213    210                                           24 hr.     368    --     323    320                                           Shakeout   92%           100%   100%                                          __________________________________________________________________________     (1) 50% phenylpropyl pyridine and 50% of a lithium salt of a carboxylic       acid.                                                                          .sup.c Pluracol 767 is a brand name for a propoxylated aromatic              aminebased polyol commercially available from BASF Wyandotte.                 .sup.d Pluracol 795 is a brand name for an ethoxylated aromatic aminebase     polyol commercially available from BASF Wyandotte.                            .sup.e a blend of HISOL 10 and kerosene.   Cores made as described above      were observed to collapse and flow out of the casting without using an     agitation mechanism and without the application of any external mechanical     energy.

EXAMPLE 12

An aromatic amine polyol was prepared by propoxylating one mole ofortho-polylenediamine with 4.2 moles of propylene oxide. A 40% solidssolution of the aromatic amine polyol was prepared by dissolving thepolyol in isophorone. This solution is referred to as Part I. Apolymeric isocyanate, Mondur MR, is referred to as Part II. A nearlystoichiometric amount of polyisocyanate to completely react with thehydroxyl groups of the polyol was used.

Wedron 5010 sand (washed and dried, fine grained silica sand, AFSGFN 66)was placed in a suitable mixing apparatus. Part I was admixed with thesand until a uniform coating was provided. Incorporated in Part I was a33% solution in dipropylene glycol of a urethane catalyst,triethylenediamine, commercially available under the brand name DABCO.This catalyst is a well-known urethane catalyst. Based on the weight ofPart I, 1.0% catalyst was used. Part II was added to the coated sand andblended until a homogeneous sand mix was prepared. One and a halfpercent (11/2%) of total binder (55% Part I and 45% Part II) by weightof sand was used.

The mix of sand, polyol, catalyst and polyisocyanate was placed in acore box and standard tensile briquettes, known as "dog bones", wereprepared. A work time of nine minutes and a strip time of twenty minuteswas achieved. Tensile strength of psi after 2 hours and 24 hours were292 and 313, respectively.

The "dog bone" cores were used in shakeout studies as described inExample 1. Shakeout was 100%.

EXAMPLES 13-15

Using the procedures described in Example 12 dog bone test cores wereprepared using the components and methods as described below. The coreswere used in shakeout tests using aluminum castings as described inExample 12.

    ______________________________________                                                 Example 13                                                                            Example 14   Example 15                                      ______________________________________                                        Sand       Wedron    Wedron       Wedron                                                 5010      5010         5010                                        Amine      Meta      CURITHANE.sup.103                                                                          Anile                                       Component  phenylene an anile formalde-                                                  diamine   hyde resin from                                                               Upjohn                                                   Alkylene   Propylene Propylene oxide                                                                            Propylene                                   Oxide      oxide                  oxide                                       Mole Ratio 4.2:1     4.2:1        2.2:1                                       AO:amine                                                                      Amine Polyol                                                                  Polyisocyanate                                                                           Mondur    Mondur MR    Mondur MR                                              MR                                                                 Solvent in 60%       60% Isophorone                                                                             60% (X)                                     Amine Polyol                                                                             Isophorone                                                         Solvent in None      None         None                                        Polyisocyanate                                                                Catalyst   None      None         1% Babco                                    Work Time  45 min.   70 min.      70 min.                                     Strip Time 78 min.   101 min.     140 min.                                    Percent    1.5%      1.5%         1.5%                                        Binder                                                                                   55% Part I                                                                              73% Part I   61% Part I                                             45% Part II                                                                             27% Part II  39% Part II                                 Tensile Strength                                                              in psi:                                                                       2 hr.      145       23                                                       4 hr.      307                                                                24 hr.     320       140          180                                         Shakeout   89%       100% 74%                                                 ______________________________________                                         (X) a blend of butyl cellosolve acetate (40%) and HISOL 10 (20%)         

Cores made as described above were observed to collapse and flow out ofthe casting using an agitation mechanism, with the application ofexternal mechanical energy.

What is claimed is:
 1. Process for casting lightweight metalscomprising:(a) Forming a foundry mix said mix comprising an aggregate, apolyisocyanate and an amine polyol wherein the aggregate comprises atleast 90% by weight of said mix; (b) Shaping said mix to form a foundryshape; (c) Allowing said mix to cure after said shape has been formed;(d) Forming a shaped lightweight metal casting by using said curedshaped mix and by casting melted light weight metal into contact withsaid cured shaped mix; and (e) Removing the cured shaped mix from saidlight weight metal casting;
 2. The process of claim 1 wherein the aminepolyol comprises an reaction product of an amine compound and analkylene oxide.
 3. The process of claim 1 wherein the aggregate is sand.4. The process of claim 2 wherein the amine compound is ammonia.
 5. Theprocess of claim 2 wherein the amine compound is an aromatic amine. 6.The process of claim 2 wherein the amine compound is an aliphatic amine.7. The process of claim 2 wherein the alkylene oxide is propylene oxide.8. The process of claim 2 wherein the alkylene oxide is ethylene oxide.9. The process of claim 1 wherein the polyisocyanate is present as asolution of an organic solvent.
 10. The process of claim 1 wherein theamine polyol is present as a solution of an organic solvent.
 11. Theprocess of claim 1 wherein the amine polyol is present as a solution ofwater.
 12. The process of claim 1 wherein the casting of light weightmetal is done at a temperature below 2000° F.
 13. Process for castinglight weight metals comprising:(a) Forming a mix said mix comprising anaggregate, a polyisocyanate and polyol wherein said aggregate comprisesat least 90% by weight of said mix and wherein said polyol consistsessentially of an amine polyol; (b) Shaping said mix to form a foundryshape. (c) Allowing said mix to cure after said shape has been formed;(d) Forming a shaped light weight casting by using said cured shaped mixand by casting melted light weight metal into contact with said curedshaped mix; and (e) Removing the cured shaped mix from said light weightmetal casting.
 14. The process of claim 13 wherein the amine polyolcomprises an reaction product of an amine compound and an alkyleneoxide.
 15. The process of claim 13 wherein the aggregate is sand. 16.The process of claim 14 wherein the amine compound is ammonia.
 17. Theprocess of claim 14 wherein the amine compound is an aromatic amine. 18.The process of claim 14 wherein the amine compound is an aliphaticamine.
 19. The process of claim 14 wherein the alkylene oxide ispropylene oxide.
 20. The process of claim 14 wherein the alkylene oxideis ethylene oxide.
 21. The process of claim 13 wherein thepolyisocyanate is present as a solution of an organic solvent.
 22. Theprocess of claim 13 wherein the amine polyol is present as a solution ofan organic solvent.
 23. The process of claim 13 wherein the amine polyolis present as a solution of water.
 24. The process of claim 13 whereinthe casting of light weight metal is done at a temperature below 2000°F.
 25. The process of claim 13 where the polyol consists essentially ofan amine polyol and a phenolic resin.
 26. The process of claim 13wherein the polyol comprises an amine polyol and a non-aromatic hydroxycompound.
 27. The process of claim 13 wherein the light weight metalcast is aluminum.